I assume that you're trying to create a menu item to a PDF file by entering the PDF file's URL. You can access the PDF if you enter the exact same (to the very last letter) URL directly in your browser. If this description is accurate then no, this does not come from Admin Tools. In fact, the URL Joomla uses in the HTML when displaying the menu is the target URL you entered, the one you claim works.
What really happened: you mistyped the URL in your menu item.
Please remember that file names are case sensitive, e.g. https://www.example.com/images/foo.pdf, https://www.example.com/images/foo.PDF, https://www.example.com/images/FOO.pdf and https://www.example.com/Images/Foo.PDF are four different URLs pointing to four different files.
Nicholas K. Dionysopoulos
Lead Developer and Director
🇬🇷Greek: native 🇬🇧English: excellent 🇫🇷French: basic • 🕐 My time zone is Europe / Athens
Please keep in mind my timezone and cultural differences when reading my replies. Thank you!